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Synthesis and properties of the waterborne polyurethane modified with the hydroxyl-terminated polybutadiene  
Synthesis and properties of the waterborne polyurethane modified with the hydroxyl-terminated polybutadiene
资料类型: PDF文件
关键词: waterborne  polyurethane  hydroxyl-terminated  polybutadiene  coating  resistance  for  
water  and  solvent  
资料大小: 1782K
所属学科: 分子表征
来源: ICAFPM 2011先进纤维与聚合物材料国际学术会议(2011.8.15~17,上海)
简介:
Theresistanceofnormalwaterbornepolyurethanecoatingsforwaterandsolventwouldbelowerthanthesolvent-basedpolyurethane.Inordertoimprovetheresistanceforwaterandsolvent,itwasinvestigatedthatawaterbornepolyurethane(WPU)weremodifiedbyhydroxyl-terminatedpolybutadiene(HTPB),andtheinfluenceofcontentofHTPBand-COOH(COOHwt%=1.5%,HTPBwt%≤35%)onWPUstabilityanddiameterwerestudied.Itwasmoresteadythatthecontentofcarboxylgroupsis1.5wt%orhigherthan1.5wt%andthecontentofHTPBislowerthan35wt%.ThewaterbornepolyurethanestructurewouldbestudiedbyATR,IRandTEM,andtheimprovementmechanismofitsresistanceforwaterandsolventanditsmechanicalpropertieswasdiscussedinthispaper.ItwerefoundthatcarboxylateandcarbamatesegmentsasthestronghydrophilicsegmentinthefilmsofWPUareexcludedfromthesurfacethefilmsofWPU,andthehydrophobicsurfacepropertiesofthefilmsofWPUwereimproved,andsomemechanicalpropertieswerepreservedorimprovedtosomeextent.
作者: CHEN Jianbing, GUO Qiang, ZHANG Sigang, ZHAO Zhengping
上传时间: 2011-09-22 14:11:19
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